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If it's on the field, you can use it as a link material, but you can also activate it by pulling it from the union carrier's equipment and sending it to his GY

(2) When your opponent activates a monster effect (Quick Effect): You can discard 1 Skyfang Brigade card

As is expected in modern Pokmon sets, there are some Special Illustration cards and other unique treatments that can add to the collectible value of the sets cards

In this regard, Pokemon EX have more in common with the Pokemon V of today

However, grading costs money, and turnaround times can vary, so its best reserved for cards worth at least 50100 or those with sentimental significance