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Bandai says that it was released in September 1996 (It was also said that there was no exact release date left.) In summary The answer of title, Pokemon cards printed earliest is the Pokemon card released before Sep 1996

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Furthermore, Arkana used the stripper technique, one of the many card-cheating techniques he learned from his previous profession, and cruelly sacrificed his monsters to win, all the while treating his monsters as dispensable slaves and claiming that ruthlessness to even one's own "slaves" is necessary to victory